B4H4and B4(CH3)4as Unique Electron Donors in Hydrogen-Bonded and Halogen-Bonded Complexes
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چکیده
منابع مشابه
From charge transfer to electron transfer in halogen-bonded complexes of electrophilic bromocarbons with halide anions.
Experimental and computational studies of the halogen-bonded complexes, [R-Br, X(-)], of bromosubstituted electrophiles, R-Br, and halide anions, X(-), revealed that decrease of a gap between the frontier orbitals of interacting species led to reduction of the energy of the optical charge-transfer transition and to increase in the ground-state charge transfer (X(-) → R-Br) in their associates. ...
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ژورنال
عنوان ژورنال: The Journal of Physical Chemistry A
سال: 2016
ISSN: 1089-5639,1520-5215
DOI: 10.1021/acs.jpca.6b05367